
In a well-known chemistry demonstration in the secondary education, a professor uses the electricity first to separate the liquid water in his component gases, hydrogen and oxygen. Then, combining the two gases and lighting them with a spark, the instructor transforms the gases into water with a very audible noise.
Some scientists in the University of Illinois have discovered a new form of obtaining water, and without necessity of the explosion. They cannot only obtain the water starting from unlikely initial materials, as the alcohols, but rather their work can also take to produce better catalysts, and less expensive cells of fuel.
Zachariah Heiden and Thomas Rauchfuss has discovered that hidruros of non conventional metals can be used for a chemical process that is essential part of the process of formation of the water.
The professor of chemical Thomas Rauchfuss,
to the left, and the student
graduated Zachariah Heiden
A molecule of water is composed by two atoms of hydrogen and an oxygen atom. But it cannot simply take two atoms of hydrogen and to hit them with an oxygen atom. The real reaction of formation of the water is a little more complicated. To produce two molecules of water (H2O), two molecules of hydrogen diatómico (H2) they should combine with a molecule of oxygen diatómico (O2); and energy will be liberated in the process.
This reaction (2H2 + O2 = 2H2O + Energy) it is known for two centuries, but up to now nobody has made it work in a homogeneous solution.
This very well-known reaction also describes what happens inside a cell of fuel of hydrogen.
In a typical cell of fuel, the gas hydrogen diatómico enters for an end of the cell, and the gas oxygen diatómico enters for the other end. The molecules of hydrogen lose their electrons and they are loaded positively through a process denominated oxidation, while the oxygen molecules win four electrons and they are loaded negatively through a process denominated reduction. The loaded oxygen ions negatively combine positively with the loaded ions of hydrogen, to obtain water and to liberate electric power.
The side difficult of the cell of fuel it is the reaction of reduction of the oxygen, not the reaction of oxidation of the hydrogen. "However, we have checked that the new catalysts for the reduction of the oxygen can also take to new chemical means for the oxidation of the hydrogen", Rauchfuss explains.
Rauchfuss and Heiden have investigated a relatively new generation of catalysts for their use in the reduction of the oxygen. The investigators have concentrated especially on certain catalysts based on the iridium. They found that the complex effects of the iridium produce the oxidation of the alcohols so much, as the reduction of the oxygen.
"Most of the compounds react with the hydrogen or with the oxygen, but this catalyst reacts with both", Heiden underlines.
The new catalysts could lead to the future development of more efficient cells of fuel of hydrogen, diminishing their cost substantially.